Is this is correct grammar at the most earliest?

Here's why:

* "Earliest" is already the superlative form of "early," meaning it indicates the absolute earliest point in time. You don't need to add "most" in front of it.

* The correct phrasing is "at the earliest" or "as early as possible."

For example:

* "I'll be there at the earliest."

* "I'll try to arrive as early as possible."