To use it as an adverb, you would need to use the word "badly," or another synonym of "bad."
Here are some examples:
Incorrect: "He played the worst in the entire game."
Correct: "He played the worst of the entire game." (using "worst" as an adjective)
Correct: "He played badly in the entire game." (using "badly" as an adverb)
Incorrect: "The movie was worst than I expected."
Correct: "The movie was the worst I've ever seen." (using "worst" as an adjective)
Correct: "The movie was worse than I expected." (using "worse" as a comparative adjective)
Correct: "The movie was badly made." (using "badly" as an adverb)