Verb:
* Past participle: "He was concerned about the safety of his family."
* Past tense: "She concerned herself with the details of the project."
Adjective:
* Describing a state of worry: "He had a concerned look on his face."
* Describing someone who cares about something: "The concerned citizen contacted the authorities."
So, to determine whether "concerned" is a verb or an adjective, you need to look at how it's used in a sentence.